Academy City's Daihasei Festival is approaching, and the festival's steering committee is charged with recruiting at least two Level 5s to take the athlete's pledge during the opening ceremonies. However, getting volunteers proves to be a challenge.

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The Tokiwadai team competes in the Balloon Hunter event, but due to a case of mistaken identity, one of the Sisters substitutes for Mikoto. Yoshio Baba feeds the other school's team with data on the Tokiwadai competitors, with surprising results.

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Saten's quest for Shadow Metal ends up landing her in trouble. Uiharu notices something amiss with the website Saten was browsing. Mikoto learns that Wannai did not get her gym uniform returned, prompting her to go track down her Sister.

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With her closest friends now giving her the cold shoulder, Mikoto feels isolated and helpless, but finds a surprise ally in Kongo. Kongo tries to track down any clues that will lead her to the whereabouts of Mikoto's missing "twin sister."

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Saten carries an injured Kongo to safety, while Awatsuki and Wannai tackle Yoshio Baba and his robotic Great Danes. Mikoto spots Saten with Kongo in an ambulance, blames herself for getting Kongo hurt, and determines to set things right.

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With Kongo out of danger, Awatsuki finishes the task of having her psychometrist friend probe the kitten's memories. What Saten hears gives her pause, and she turns to Kuroko for advice.

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Mikoto and Shokuho continue pursuing Gensei Kihara using their own individual methods. Kuroko attempts to identify the girl who abducted Uiharu and Misuzu. Saten decides to investigate an abandoned factory that may be connected to the case

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Shokuho and Mikoto find themselves in a traffic jam, and Shokuho demonstrates a tremendous example of her ability. The background behind the Exterior project is revealed, as well as Shokuho's connection to one of the original Misaka clones

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Kozaku uses Exterior to make her way into Mikoto's mind, convincing her to attack the building without windows. Before she can go after Gensei, Shokuho must contend with Kozaku's puppet, until help arrives from an unexpected source.

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Kamijo and Sogiita find that at best, they can only slow down Mikoto's transformation. Kuroko continues to search for Kozaku while dodging her puppet. Gensei pursues Shokuho for the access code that will let him unlock Exterior's potential

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To counter the Doppelganger's giant monster form, Mikoto creates a giant magnetically-induced monster of her own. As the two do battle, it becomes evident that the Doppelganger has an ultimate objective other than combat in mind.

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